|
Wool,
the hair of various breeds of sheep, is a warm springy fibre. It’s scaly
structure led in the past to unwanted felting (matting of fibres) and
shrinkage in laundering but modern finishing treatments have now overcome
these difficulties; similarly, attack by the clothes moth is no longer
a problem. Wool
has a natural crimpiness, which gives it good elasticity, bulk, crease-resistance
and durability. Its strength when wet is less than when it is dry. Important
properties of wool are a dry strength of 11.5 to 13 cN/tex, a breaking
elongation of 30 to 40% and a moisture regain of 16 to 18%. Technologically,
the diameter, or fineness, of the wool fibre is probably the most important
property. It is determined to a large extent by the grade assigned to
a lot, or batch, of wool. Diameters range from 16 microns in the finest
Merinos to over 40 microns in the coarsest long-wool types. Staple length
generally increases with increasing fibre diameter, ranging from four
to eight centimetres for fine Merino up to 35 centimetres for coarse Cotswold
wool. Staple length is lower than mean fibre length because of the crimp
that results in a helical configuration in an individual fibre and an
uni-planar wave in the staple. Wool
fibres are hygroscopic, absorbing water from a moist atmosphere in a reversible
way. Because most fibres are dependent on moisture content, this characteristic
is extremely important, especially in numerous processing steps, including
carding, combing, spinning and weaving. Relative humidity in the processing
plants must be controlled for optimum processing conditions. Upon uptake
of water , the fibre swells anisotropically (unequally), increasing up
to 16% in diameter while the change in length is only about 1.2 to 1.5%.
The ability of wool fibres to absorb and release moisture contributes
to wearing comfort in garments made of wool. In
the UK alone there are 34 main breeds of sheep and a further 43 rare breeds
and hybrids. When wool fibres have been processed it is not possible to
say with confidence from what breed of sheep or country they have originated
because wool fibres from several breeds have the same microscopical appearance.
There are four main types of wool fibre: fine, coarse, outercoat and kemps.
Each type has a characteristic scale pattern so that it is possible to
distinguish between types, although it is not possible to assign a type
to a breed of sheep. Wool
fibres are generally white, with the finer fibres having a circular cross
section and the coarse fibres being more irregular in contour. Kemp fibres
are usually chalky white in appearance, very coarse and brittle, with
a long tapering tip and a taper over a short distance to the root end. An
important aspect of the environmental impact of wool processing is the
use of pesticides on sheep. Although the problem has been minimised over
recent years with the introduction of tighter restrictions or even bans
on the use of some formulations, this is still a major concern since these
toxic chemicals make their way into rivers. Another
impact at this early stage which is maybe less obvious, is the methane
generated globally by the many hundreds of millions of sheep. Methane
is a powerful greenhouse gas and contributes to the effect of global warming. Again,
as with cotton there is also the effect of transporting huge quantities
of textiles across the globe with the associated fuel usage and fume generation
problems. The
scouring of the raw wool, the next stage, is a process which produces
a liquid effluent with a very high organic load and solids content and
varying levels of pesticide contamination. The highly polluting nature
of this waste and the strict discharge consents associated with the process
means that scourers have to treat their effluent on-site. Another
environmental problem is that many of the dyestuffs available for obtaining
good dark shades on woollen fabric or yarn are mordant dyes containing
chromium. The discharge of chromium is strictly controlled and so companies
are being forced into using alternatives or consider on-site effluent
treatment. In
the carpet industry permethrin, another pesticide, is added to the yarn
that goes into making contract carpets, this is a quality requirement
to protect the wool from moth attack. The effluent from this process must
therefore be treated and continually monitored. |
||